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Worksheet 22 on Introduction to Chemistry 1 |, Study notes of Chemistry

hw Material Type: Notes; Class: Chemistry 1 - Introduction; Subject: Chemistry; University: The Art Institute of Atlanta;

Typology: Study notes

2011/2012

Uploaded on 02/22/2012

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Worksheet of Chapter 22
1. Draw the major organic products for following reactions.
OH
OH
O
SOCl2
Cl
O
+N
H(excess)
OH
O
+HO H2SO4
H
N
O
NaOH
H2O
O
O
O
H3O+
Br
1) NaCN
2) -OH, H2O
H3O+
CN
O
OO+NH2
(excess)
pf2

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Worksheet of Chapter 22

1. Draw the major organic products for following reactions.

OH

OH

O

SOCl 2

Cl

O

+ N

H (excess)

OH

O

+ HO^ H^2 SO^4

HN

O

NaOH H 2 O

O

O

O

H 3 O +

Br

  1. NaCN
  2. -^ OH, H 2 O

CN^ H 3 O^ +

O

O O

+ NH 2

(excess)

O

O - OH

H 2 O

OH

O

Cl

Br H D

NaCN

COOH

H D CH 3 CH 2 OH

H +

2. Draw the stepwise mechanism for the following reaction.

O

O -

OH

H 2 O HO^ O^ -

O

3. Rank them from most reactive to least reactive in nucleophilic acyl substitution.

O

O

O

O

NO 2 O

O

OCH 3