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Titration Lab Report, Lab Reports of Chemistry

This is the final formal lab activity of the chemistry

Typology: Lab Reports

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CHEMISTRY 11 Acid-Base Titration FULL FORMAL LAB Toombs
Acid/Base Chemistry: Titration Lab
THE FINAL FORMAL LAB ACTIVITY of the Chemistry 11 Course
What is a Titration?
A titration is an analytical procedure used to determine the accurate concentration of a sample by
reacting it with a standard solution. One type of titration uses a neutralization reaction, in which an
acid and a base react to produce a salt and water:
In equation 1, the acid is HCl (hydrochloric acid) and the base is NaOH (sodium hydroxide).
When the acid and base react, they form NaCl (sodium chloride), which is also known as table salt.
The titration proceeds until the equivalence point is reached, where the number of moles of
acid (H+) is equal to the number of moles of base (OH -). The moles of acid and base are related by
the stoichiometry of the balanced equation. This equivalence point is usually marked by observing a
colour change in an added indicator. The moment where the colour of the indicator changes is called
the endpoint.
In a titration, the standard solution (of known concentration) is in a buret, which is a piece of
glassware used to measure the volume of solution to a great degree of accuracy. The solution that you
are titrating (of unknown concentration, but the volume is accurately measured) is in an Erlenmeyer
flask, which should be large enough to accommodate both your sample and the standard solution you
are adding.
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Acid/Base Chemistry: Titration Lab

THE FINAL FORMAL LAB ACTIVITY of the Chemistry 11 Course

What is a Titration?

A titration is an analytical procedure used to determine the accurate concentration of a sample by reacting it with a standard solution. One type of titration uses a neutralization reaction, in which an acid and a base react to produce a salt and water: In equation 1, the acid is HCl (hydrochloric acid) and the base is NaOH (sodium hydroxide). When the acid and base react, they form NaCl (sodium chloride), which is also known as table salt. The titration proceeds until the equivalence point is reached, where the number of moles of acid (H

) is equal to the number of moles of base (OH

  • ). The moles of acid and base are related by the stoichiometry of the balanced equation. This equivalence point is usually marked by observing a colour change in an added indicator. The moment where the colour of the indicator changes is called the endpoint. In a titration, the standard solution (of known concentration) is in a buret, which is a piece of glassware used to measure the volume of solution to a great degree of accuracy. The solution that you are titrating (of unknown concentration, but the volume is accurately measured) is in an Erlenmeyer flask, which should be large enough to accommodate both your sample and the standard solution you are adding.

A buret is used because the volumes can be measured very precisely ( + 0.05 mL). ( + ½ of the marking on the glassware). Be sure you are reading volumes properly, from the bottom of the meniscus. For example the volume on the buret below would be 18.50 + 0.05 mL If this was your final volume reading on your buret, it would be 42.30 + 0.05 mL This volume information would be written in a data table like this: INITIAL BURET READING: 18.50 + 0.05 mL. FINAL BURET READING: 42.30 + 0.05 mL TOTAL VOLUME OF NaOH used in the Titraion: Vf – Vi = 42.30 – 18.50 = 23.80 ml The acid is typically added to the Erlenmeyer flask in a specific volume (usually 10.0 or 25.0 mL) using a pipette which also measures volumes very precisely. The sample size (in mL) of the unknown is called an “aliquot.” A typical pipette

Titration Lab Procedure DAY ONE:

1. Rinse the burette with H 2 O. (Check valve and seal; DO NOT put the buret under the water tap!!

Use a beaker filled with H 2 O to perform these rinses and then dump the water rinsings into the sink)

2. Rinse with <10 ml of NaOH. (Discard in waste container)

3. Fill the burette with NaOH until the meniscus rests at 0.0 0 ml.

4. Record the accurate molarity of the NaOH.

5. Obtain exactly 10 .0 mL of HCl solution in Erlenmeyer flask.

6. Add 3-5 drops of bromthymol blue indicator to the Erlenmeyer flask.

7. Add the NaOH from the burette, slowly, dropwise, to the HCl sample in the

Erlenmeyer. Keep one hand on the valve and the other hand constantly swirling

the Erlenmeyer flask. This step must all be done by ONE PERSON at a time.

8. Stop when the indicator turns green.

9. Each person in the lab group must complete the titration steps 5 to 8.

You will likely NOT be successful the first time you try this, as you have no idea how many mL of NaOH it will take to neutralize your unknown acid sample. Consider the following tips:

  • Do a rough titration, adding ~1 mL of NaOH at a time to find the approximate volume needed for neutralization
  • Once you have an idea of the volume at which the colour will change, then repeat the titration until you have 2 “good” results. (Acceptable titration practice requires two results that are within 0.1 ml of each other)

CLEAN UP at the end of the titration:

Drain the NaOH out of the burette (discard unused solutions in waste container), and rinse the burette with water before putting it away. YOU CAN NOT LEAVE any NaOH inside the buret!!!! Neutralized solution in the Erlenmeyer flask can be rinsed down the drain with H 2 O Rinse all glassware with water and put all glassware away (does not have to be dried).

Copy the data table below into your lab report:

Titration of HCl

Temperature (°C)

Concentration of NaOH standard (M)

Volume of HCl sample (mL ±? mL)

Titration Trial 1: volume of NaOH (mL ±? mL)

Titration Trial 2: volume of NaOH (mL ±? mL)

Titration Trial 3: volume of NaOH (mL ±? mL)

Titration Trial 4: volume of NaOH (mL ±? mL)

Average volume of NaOH (mL ±? mL)

Titration Lab Procedure DAY TWO:

If you are starting this lab on the next day, repeat steps 1 to 4 from the DAY ONE instructions.

5. Obtain __________ mL of ___________________acid in Erlenmeyer flask

6. Add 3-5 drops of ____________________ indicator

7. Add the NaOH from the burette, slowly, dropwise, to the acid sample in the

Erlenmeyer. Keep one hand on the valve and the other hand constantly swirling

the Erlenmeyer flask.

8. Stop when the indicator turns ________________.

9. Each person in the lab group must complete the titration steps 5 to 8.

Copy the table below into your lab report:

Titration of acid

Temperature (°C)

Concentration of NaOH standard (M)

Volume of __________acid sample (mL ±? mL)

Titration Trial 1: volume of NaOH (mL ±? mL)

Titration Trial 2: volume of NaOH (mL ±? mL)

Titration Trial 3: volume of NaOH (mL ±? mL)

Titration Trial 4: volume of NaOH (mL ±? mL)

Average volume of NaOH (mL ±? mL)

Calculations:

Lab Day #1) Use the successful trials to calculate an average volume of NaOH used

in the titration, and to calculate the concentration of the HCl solution.

Calculations:

Lab Day #2) Use the successful trials to calculate an average volume of NaOH used

to titrate the unknown acid, and to calculate the concentration of the acid

solution.

Get the Final [acid] for each part of the lab from TWO other lab groups.

Day 1 [acid] from two other groups: ____________ ________________

Day 2 [acid] from two other groups: ____________ ________________

You will be comparing your answer to other lab groups in your

Analysis of Accepted Value section of your lab report to calculate a

Percent Deviation (see Mrs. Toombs’ Lab Report Format outline).

Marks

2 Proper Lab Report Format throughout

1 Purpose

1 Materials

3 Procedure

3 Observations

4 Data tables

4 Calculations

Questions

3 Sources of Error

3 Analysis of Percent Deviation

3 Relevant Theory

1 Conclusion

Late labs:

Total mark from above / 40 will be scaled down to a mark / 30

And then the 2 additional questions will be marked / 10

and added to the / 30 mark above to get a new total lab mark / 40