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Order of Acid and Base Strengths, Exams of Chemistry

The correct answers and instructor comments for the order of strength for various acids and bases. It includes examples of acids and bases in the order of increasing and decreasing strength, as well as common misconceptions and usefulness of a table of ka's for answering such questions.

Typology: Exams

2021/2022

Uploaded on 09/12/2022

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The order of acid strength is:
1. HNO2 > HOCl > HNO3 > NH4+
2. HOCl >HNO3> NH4+ > HNO2
3. HNO3 > NH4+ > HNO2 > HOCl
4. HNO3 > HNO2 > HOCl > NH4+
Correct Answer: 4.
Comments to the instructor: You may or may not allow students to use a table of Ka’s, or
provide Ka’s as a hint. If students know that HNO3 is a strong acid, then the choices 1
and 2 may be quickly eliminated.
The order of increasing base strength is:
1. H2O > NH3 > CH3CO2- > CN-
2. NH3 > H2O > CH3CO2- > CN-
3. NH3 > CN- > CH3CO2- > H2O
4. CH3CO2- > NH3 > CN- > H2O
Correct Answer: 3.
Comments to the instructor: A table of Ka’s is useful.
The order of increasing acid strength is:
1. H2SO4 > HSO4- > H3PO4 > H2PO4- > HPO42-
2. HSO4- > H2SO4 > H3PO4 > H2PO4- > HPO42-
3. H3PO4 > HSO4- > H2SO4 > H2PO4- > HPO42-
4. H3PO4 > H2SO4 > HSO4- > H2PO4- > HPO42-
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The order of acid strength is:

1. HNO 2 > HOCl > HNO 3 > NH 4

2. HOCl >HNO 3 > NH 4 +^ > HNO 2

3. HNO 3 > NH 4

> HNO 2 > HOCl

4. HNO 3 > HNO 2 > HOCl > NH 4 +

Correct Answer: 4.

Comments to the instructor: You may or may not allow students to use a table of Ka ’s, or

provide Ka ’s as a hint. If students know that HNO 3 is a strong acid, then the choices 1

and 2 may be quickly eliminated.

The order of increasing base strength is:

1. H 2 O > NH 3 > CH 3 CO 2 -^ > CN-

2. NH 3 > H 2 O > CH 3 CO 2

> CN

3. NH 3 > CN-^ > CH 3 CO 2 -^ > H 2 O

4. CH 3 CO 2

> NH 3 > CN

> H 2 O

Correct Answer: 3.

Comments to the instructor: A table of Ka ’s is useful.

The order of increasing acid strength is:

1. H 2 SO 4 > HSO 4

> H 3 PO 4 > H 2 PO 4

> HPO 4

2. HSO 4 -^ > H 2 SO 4 > H 3 PO 4 > H 2 PO 4 -^ > HPO 4 2-

3. H 3 PO 4 > HSO 4

> H 2 SO 4 > H 2 PO 4

> HPO 4

4. H 3 PO 4 > H 2 SO 4 > HSO 4

> H 2 PO 4

> HPO 4

Correct Answer: 1.

Comments to the instructor: This should be an easy one, provided the student knows that

the first dissociation for H 2 SO 4 goes to completion. Common misconceptions include

Choice 4 – the more hydrogen ions, the more acidic.