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The “Extremely Explosive” Carbonyl Diazide Molecule, Schemes and Mind Maps of Chemistry

The structure of carbonyl diazide, OC(N3)2 , is exactly what you would predict from Lewis structures and VSEPR theory structures and VSEPR theory.

Typology: Schemes and Mind Maps

2021/2022

Uploaded on 09/12/2022

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The “Extremely Explosive” Carbonyl Diazide
Molecule
X. Zeng, M. Gerken, H. Beckers, and H. Willner, “Synthesis
and Characterization of Carbonyl Diazide, OC(N3)2,”
Inorg
Chem
2010
49
9694
9699
Inorg
.
Chem
.
2010
, 49
,
9694
-
9699
.
Compare the bond lengths of sodium azide to hydrogen
azide, NaN3and HN3
A) HNN-N < NaNN-N < HN-NN
B
)
HNN-N < HN-NN < NaNN-N
10
)
C) NaNN-N < HN-NN < HNN-N
D) NaNN-N < HN-NN = HNN-N
E) HN-NN = HNN-N < NaNN-N
Thanks to Margret J. Geselbracht, Reed College
2
666
66
-
...
11
2
666
66
-
...
pf3
pf4
pf5

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The “Extremely Explosive” Carbonyl Diazide

Molecule

X. Zeng, M. Gerken, H. Beckers, and H. Willner, “Synthesis

and Characterization of Carbonyl Diazide, OC(N 3 ) 2 ,”

InorgInorg. Chem.Chem 20102010 , 49 49 , 9694-9699.9694 9699

Compare the bond lengths of sodium azide to hydrogen

azide, NaN 3 and HN 3

A) HNN-N < NaNN-N < HN-NN

B) HNN-N < HN-NN < NaNN-N

10

C) NaNN-N < HN-NN < HNN-N

D) NaNN-N < HN-NN = HNN-N

E) HN-NN = HNN-N < NaNN-N

Thanks to Margret J. Geselbracht, Reed College

- 6 6 6 662 ... ^12

Wed, Sept 14

14-Sepp

Ch 3 73-

HW:

Predict bond polarity; predict boiling points

EH; relate electronegativity to structure

carbonyl diazide, OC(N 3 ) 2

The structure of carbonyl diazide, OC(N 3 ) 2 , is

exactly what you would predict from Lewis

structures and VSEPR theorystructures and VSEPR theory.

Use your skills to rank order the following bond

angles: NNN, NNC, NCO

A) NNN < NNC < NCO

B) NNC < NCO < NNN

16

) C CO

C) NCO < NNN < NNC

D) NCO = NCN < NNN

Electronegativity and size affect Bond Angles

Rank the bond

angles

A) ClSCl < FSF) l l

B) FSF < ClSSl

Which electron cloud picture corresponds to H 2 O? A B C D E

  • 6 6 6 662 ... ^18