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AQA Chemistry A-level (7405) - Colours of Metal Ions in Aqueous Solution, Lecture notes of Chemistry

Information on the colors of metal ion solutions and products for the aqa chemistry a-level (7405) specification, focusing on reactions of ions in aqueous solution. Students are expected to describe the metal, aqueous ion, and the actions of naoh, excess naoh, nh3, excess nh3, na2co3, and various metal ions such as iron(ii), copper(ii), iron(iii), and aluminium(iii). The document also mentions the changes that occur when these metal ions react with naoh and nh3, and the corresponding ppt or gas evolution.

Typology: Lecture notes

2021/2022

Uploaded on 09/12/2022

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AQA Education (AQA) is a registered charity (number 1073334) and a company limited by guarantee registered in England and Wales (number 3644723). Our registered
address is AQA, Devas Street, Manchester M15 6EX.
Reactions of metal ions in aqueous solution
Chemistry A-level (7405)
This resource (v1.4) represents colours of solutions and products (Specification reference 3.2.6 Reactions of ions in aqueous
solution). Students are expected to describe:
Metal
Aqueous ion
Action of NaOH
Action of an
excess of
NaOH(aq)
Action of NH3(aq)
Action of an excess
of NH3(aq)
Action of
Na2CO3(aq)
Iron(II)
[Fe(H2O)6]2+(aq)
green solution
Fe(H2O)4(OH)2(s)
green ppt goes
brown on standing in
air
No further change
Fe(H2O)4(OH)2(s)
green ppt goes brown
on standing in air
No further change
FeCO3(s)
green ppt
Copper(II)
[Cu(H2O)6]2+(aq)
blue solution
Cu(H2O)4(OH)2(s)
blue ppt
No further change
Cu(H2O)4(OH)2(s)
blue ppt
[Cu(H2O)2(NH3)4]2+(aq)
deep blue solution
CuCO3(s)
blue-green ppt
Iron(III)
[Fe(H2O)6]3+(aq)
purple solution
may look yellow-
brown due to some
[Fe(H2O)5(OH)]2+(aq)
Fe(H2O)3(OH)3(s)
brown ppt
(ppt may look
orange-brown)
No further change
Fe(H2O)3(OH)3(s)
brown ppt
(ppt may look orange-
brown)
No further change
Fe(H2O)3(OH)3(s)
brown ppt
(ppt may look
orange-brown)
and CO2 gas evolved
Aluminium(III)
[Al(H2O)6]3+(aq)
colourless solution
Al(H2O)3(OH)3(s)
white ppt
[Al(OH)4](aq)
colourless solution
Al(H2O)3(OH)3(s)
white ppt
No further change
Al(H2O)3(OH)3(s)
white ppt
and CO2 gas evolved
pf2

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AQA Education (AQA) is a registered charity (number 1073334) and a company limited by guarantee registered in England and Wales (number 3644723). Our registered address is AQA, Devas Street, Manchester M15 6EX.

Reactions of metal ions in aqueous solution

Chemistry A-level (7405)

This resource (v1. 4 ) represents colours of solutions and products (Specification reference 3.2.6 Reactions of ions in aqueous solution). Students are expected to describe: Metal Aqueous ion Action of NaOH Action of an excess of NaOH(aq) Action of NH 3 (aq) Action of an excess of NH 3 (aq) Action of Na 2 CO 3 (aq) Iron(II) [Fe(H 2 O) 6 ]2+(aq) green solution Fe(H 2 O) 4 (OH) 2 (s) green ppt goes brown on standing in air No further change Fe(H 2 O) 4 (OH) 2 (s) green ppt goes brown on standing in air No further change FeCO 3 (s) green ppt Copper(II) [Cu(H 2 O) 6 ]2+(aq) blue solution Cu(H 2 O) 4 (OH) 2 (s) blue ppt No further change Cu(H 2 O) 4 (OH) 2 (s) blue ppt [Cu(H 2 O) 2 (NH 3 ) 4 ]2+(aq) deep blue solution CuCO 3 (s) blue-green ppt Iron(III) [Fe(H 2 O) 6 ]3+(aq) purple solution may look yellow- brown due to some [Fe(H 2 O) 5 (OH)]2+(aq) Fe(H 2 O) 3 (OH) 3 (s) brown ppt (ppt may look orange-brown) No further change Fe(H 2 O) 3 (OH) 3 (s) brown ppt (ppt may look orange- brown) No further change Fe(H 2 O) 3 (OH) 3 (s) brown ppt (ppt may look orange-brown) and CO 2 gas evolved Aluminium(III)

[Al(H 2 O) 6 ]3+(aq)

colourless solution

Al(H 2 O) 3 (OH) 3 (s)

white ppt

[Al(OH) 4 ]–(aq)

colourless solution

Al(H 2 O) 3 (OH) 3 (s)

white ppt No further change

Al(H 2 O) 3 (OH) 3 (s)

white ppt and CO 2 gas evolved

AQA Education (AQA) is a registered charity (number 1073334) and a company limited by guarantee registered in England and Wales (number 3644723). Our registered address is AQA, Devas Street, Manchester M15 6EX. 2 of 2 Section 3.2.5.2: Substitution reactions Substitution reactions involving Cobalt (II) were previously required knowledge under the old A-level Chemistry specification (2420). These reactions and the colours of the solutions and products are no longer required knowledge for the current A-level Chemistry specification (7405). Section 3.2.5.5: Variable oxidation states Students are also expected to know the colours of the vanadium ions produced when a solution of ammonium vanadate(V) (NH 4 VO 3 ) is reduced by zinc metal under acidic conditions. Oxidation state V(V) V(IV) V(III) V(II) Species in acidic solution [VO 2 (H 2 O) 4 ]

+ [VO(H

2 O) 5 ]

2+ [V(H

2 O) 6 ]

3+ [V(H

2 O) 6 ]

2+ Colour of solution yellow blue green purple