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Solved Homework 6 for Organic Chemistry | CHEM 306, Assignments of Organic Chemistry

Material Type: Assignment; Class: Organic Chemistry; Subject: Chemistry; University: Bowling Green State University; Term: Unknown 1989;

Typology: Assignments

Pre 2010

Uploaded on 08/19/2009

koofers-user-b4p
koofers-user-b4p 🇺🇸

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Homework #6
Name: ________________________________________ Awarded points: _____of 1
Date: October 2. Due: Fri, October 4
Consider two addition reactions according to the following scheme.
Assignment #1: fill the reagents and product names in the gray boxes.
HO
OH
Vinylcyclohexane
AB
12
H2O / H+BH3H2O2
NaOH
What are the names of the products? 1)________________ 1-Cyclohexylethanol__________
2) ______________________________________________2-Cyclohexylethanol__________ .
Asssignment #2: draw the reaction mechanism responsible for the reaction pathway A. Indicate, which
structure corresponds to the first transition state and which is the semi-stable intermediate.
+HOH
H
HO
+HO
+H
OH
H
transition statemetastable
i
n
t
e
r
m
e
d
i
a
t
e
Assignment #3: draw the approximate structure of the transition state of the reaction pathway B.
H
cyclic transition state
B
H
H
?
?

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Homework

Name: ________________________________________ Awarded points: _____of 1

Date: October 2. Due: Fri, October 4

Consider two addition reactions according to the following scheme. Assignment #1: fill the reagents and product names in the gray boxes.

HO

OH

Vinylcyclohexane

A B

H 2 O / H

BH 3 H^2 O^2

NaOH

What are the names of the products? 1)________________ 1-Cyclohexylethanol__________

  1. ______________________________________________2-Cyclohexylethanol__________.

Asssignment #2: draw the reaction mechanism responsible for the reaction pathway A. Indicate, which structure corresponds to the first transition state and which is the semi-stable intermediate.

  • H^ OH

H

  • HO

HO

H

OH H

transition state metastable intermediate

Assignment #3: draw the approximate structure of the transition state of the reaction pathway B.

H

cyclic transition state

B

H

?? H