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CHEM (^3104) Quiz 1
Give the best answer to '"'€ ach question below. Show your reasoning where ap propriate.
1. (3 points) 'Write out the full electronic configuration for carbon. Circle the representa
tion of the valence electrons.
~
3 Is~~
2. (3 points) Indicate the hybridiza.tion of each carbon atom in propene, H 2 C=CHCH 3.
{r&q{l5 If(/'<" II J..,~ d< - ~ble voJ
{' (^) rio... ,5 5/ 1 h 7
br ;J,z-"j
3. (2 points) Sketch t.he orbitals that form bonds between t.he t.wo atoms illvolved in the
double bond in prop(~ ne.
r
- (2 points) How rnany antibonding molecular orbitals are there in propene?
CHEM 3104 Quiz 2 Name:^ --------'-e._^ 0'b_b-+I----.!...-'----,f^05 ___^ Vl
Give the correct IUPA name for each compound below.
1. (2 points).
[ c~ CH (^3) /). I /-- 1 cflo Cflo cflo Cff- CH, cflo CH,
2. (2 point.s).
o
~o
e
(2 points).
(2 points)
CI CI
CI
- (2 points )
OH
o (^) .', / Br ~
, ~.~ (U~'1:;;'f7{ f~ ;0;:-;;/
t^ 'I^ -^ 1-^ ,0^ t^ fl^ :^ ~^ {^0 l J - 'j(O :; - r:r.f'Of U
CHEM (^3104) N arne: ----Lg~ o~ b~ =-.::.--=-=---:...--
Give the best answe
Quiz 4
Show your reasoning where ap propriate.
1. (4 points) Give th e o:)timal reaction co nditions for each of the following reactions.
H;,.. ~ -PI; ,t /^ to - Pi/c., '^.^ U'.^ r"'^ .... fd / () pC ; (). ~ /0:
o
RGOOH
2. (4 points) Give a correct IUPAC nam e for each of the following compounds.
o -J.-e y h ~ 1'
6r d; J.. - J ~ef~ Y ( X '(~r1e
o
I
3. (2 points) List th e h,llowing compounds in o rd er of increasing stability.
2
5 I
OH OH
t
representation,
I ,
C~(;l,.CH
U 3 ---H
HO-+-- H
1, BH / THF
CHEM (^3104) Quiz 5 Name:
Give the best answer to 'a question below. Show your reasoning where ap propriate.
1. (2 points) Circle the chiral ca rbons in the compound below,
CI
o/'--......
CI
2, (4 points) Give the correct IUPAC name for each of the compounds below,
I
y
tt-y( ,^ '. Br :;l. ." <
0 "^ :
.( ~Ii ,,'" (^) '{ /1. I ~ Y
)(
, 1 ,{ /' F^ CH^3 '(^ Br \ (^) '..:;,
C~~ r:
--' ) - '3 -1(;\0(0 - 2) 3-JiY"cfhyl YlO~"VI!'
3, (2 points) How many ~tereo i some r s exist for the com pound below?
3
4, (2 points) Dr aw the major products of the reaction below, including stereochemical
Quiz (^7) Name:
Give the best answer to each question below. Show your reasoning where ap propriate.
- (6 points) Give the correct IUPAC name to each compound belmv.
3- c~'(J - 3'}
F ---+--CI 3
(5)- 5-' I:xy -:J-o{
- (4 points) Give the major product or ideal reaction conditions for each reaction blow. or 1-
2
HI rt, flut""' I (.
+"';5 a'V'( IO(f'I
Y h ~j h A,
CHEM 3104 Quiz 8 Name:
Give the best answer to each question below. propriate.
l. (2 points) Arrange t he following in order of decreasing
suhstitution: CH3Br. CH 3 Cl, CH 3F, CH3I.
Show your reasoning where ap
rea ct ivity toward nucleophilic
2. (2 point.s) Arrange the follmving in order of decreasing r eact ivity in an SN2 reaction.
3. (2 pO.ints) Arrange the a lky~ ides above in order of decreasing reactivit.y in an SN 1
) reactlon.^ _
O? r ~e (far ~ I'~' i.e
- (4 points) Give t.he major s ubstitution products for each of the following reactions.
eN
~~Br
CI-IEM 3101 (B Quiz 10 Name,
Give the best answer to each question below. Show your reasoning where ap propriate.
- (10 points) Give the rmtjor product or optimal reaction conditions for each of the fol lowing reactions.
G ~~~ H /
H
HBr
Hel
/y
Ct
~Li
1
CHEM (^3104) Quiz 11 N arne:^ _t^ ~^ b^ b^ -7-'1^ -----,-A^ -=--Y1^ ^ -I^ s^ 1,
Give the best answer to each question below. Show your reasoning where ap propriate.
- (10 points) Give the major product or optimal reaction conditions for each of the fol lowing reactions.
?l CI (^2) hu
NfJ
Br
o
~Li
THF
HBr
ROOR
