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Refractory lecture slides, Lecture notes of Powder Metallurgy

Refractory lecture slides for course that describe definition, types, example and uses of it

Typology: Lecture notes

2018/2019

Uploaded on 06/12/2019

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Refractory manufacturing
Refractory testing
and
Refractory properties
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Refractory manufacturing

Refractory testing

and

Refractory properties

What is refractory?

Is it a material which should withstand high temperature only?

The right definition is that it should withstand high temperature,resistance to thermal and thermo chemical load, posses high volume stability, resistant to erosion and abrasion, be tough , and resistant to chemical corrosion etc. Or otherwise it should have high RUL, high PCE, low conductivity , high hot MOR, high creep resistance and optimum CCS etc

Overall it is a compromise with all the above properties.

Choice of refractories depend on the operating and mechanical

conditions of the kiln.

There is no refractory material which posses all the above

properties 100 %

In general any material which in service > 600 deg C is called refractory

Fire Clay bricks

refractory clays Kaolins extended with chamotte or non plastic argillacious matter unwetted by water Al2O3 content = 30 to 45 %

High alumina bricks

**1)Cyanite,andalusite,and siliminite

  1. natural hydrated alumina(hydrargillite,bohemite,and disapore contained in bauxite) 3)Artificial calcined hydrated alumina, and natural and electro fused alumina ( Alpha -alumina or**

Class A =45 - 60 % Al2O Class B = 60 - 70 % Al2O Class C = > 75 % Al2O Silica bricks Dinas

Magnesia bricks

Magnesit ( MgCO3), Dolomite ( MgCO3.CaCO3), Mg(OH)2,Mgo Obtained from dolomite,saline water and sea water

Spinel bricks

MgO and Al2O3 together sintered or fused MgO from sea water and alumina from alumina industries ,alpha alumina etc)

Raw materials used for manufacturing of bricks

Acidic (^) Basic

neutral

Raw material user

Melting point of pure refractory oxide

SiO2 Al2O3 Cr2O3 CaO ZrO2 MgO

Deg c

Classification of refractories regarding melting point and alkalinity

14 13 12 11 10 9 8 7 6 5 4 3 2 1

3000

2750

2500

2250

2000

1750

1500

melting point Deg c

pH value

Cao

MgO

Al2O

ZrO

Cr2O

SiO

basic neutral acidic

SIC crystals ( Silicon carbide)

  • ZrSiO
  • Zircon crystals ,ZrSiO

Refractory manufacturing process

Schematic diagram of refractory manufacturing

Rough crushing

Raw material

middle crushing distribution^

fine crushing

Storage by Grain size

Measuring quantity mixing moulding

drying

firing

inspection (^) packing shipping

Refractory clay mine

Opencast mining

Under ground mining

Hydraulic press

Iso static press machine

Tunnel kiln

Important refractories used in

cement industry

Magnesia containing bricks _ mag chrome, mag spinel,

dolomite,hercynite, galaxite

based,

zirconia based

High alumina bricks - 60 - 70 % Al 2 O 3

Fire clay bricks - 30 % Al 2 O 3

Light weight insulating bricks

Unshaped refractories or castables - conventional,

low cement castable,

ultra low cement castables,

insulation castables