Chem 212 Quiz #3 – Ch 19 and 20 S2009
Good morning! Ask me questions on this if you need to, and good luck!
1) (16 points) Predict Products: please give the Major Organic Product from each
reaction. Include stereochemistry wherever appropriate. If there is no reaction please
write NR. Please don’t write mechanisms here; workout answers on scratch paper.
a
b
c
d
f
g
h
1. O3, -78oC
2. Zn, H2O
H2, Pd/C
1. O3, -78oC
2. Zn, H2O
H2, Pd/C
KMnO4
NaOH, cold
KMnO4
H2SO4
OH
O1. LiAlH4
2. NH4Cl
1. NaBH4
2. NH4Cl
eNH2
XS CH3Br
O
1)
2) NH4Cl
N
HO
heat
N
SO42-
?
2
"pH balanced shampoo"
N
H
N
HNO3
(CH3CO2)O
FeBr3
300oC
1. O3, -78oC
2. H2O2
KMnO4
NaOH, cold
Problems f, g and h are one point extra-credit problems.
i
j
k
l
m
n
o
p
