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Quiz 20 for Carboxylic Acids - Organic Chemistry | CH 243, Quizzes of Organic Chemistry

Material Type: Quiz; Professor: Cammack; Class: Organic Chemistry; Subject: Chemistry; University: Chemeketa Community College; Term: Spring 2009;

Typology: Quizzes

Pre 2010

Uploaded on 08/16/2009

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koofers-user-gj0 🇺🇸

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CH243 Name _________________
Quiz Chpt 20 Carboxylic Acids
Due 4/14/09
1. Calculate the pKa for Lactic acid (Ka = 8.4 x 10-4) Show the equation.
2. Rank in order of decreasing acidity. (#1 being the strongest acid.)
3. Complete the following reactions giving reagents or products as needed. More than one step may be required:
A.
B.
1)
2) H3O+
NaCN
Br
C.
CH2CH2OH CH3
CH3CH2CH2C
O
OH
Name ___________
2) CO2
3) H3O+
1) Mg Cl OH
O
C
O
OH
OH CH2C
O
OH
OH
C
H
O
CH2CH2OH CH3
CH2C
O
OH CH3
CH C
O
OH
Br
CH3CH2OH
C
O
OH
N
O
O
pf2

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CH243 Name _________________ Quiz Chpt 20 Carboxylic Acids Due 4/14/

  1. Calculate the pKa for Lactic acid (Ka = 8.4 x 10-4) Show the equation.
  2. Rank in order of decreasing acidity. (#1 being the strongest acid.)
  3. Complete the following reactions giving reagents or products as needed. More than one step may be required: A.

B.

2) H 3 O+

Br^ NaCN

C.

CH 3 CH 2 CH 2 C CH 3 CH 2 CH 2 OH

O

OH

Name ___________

2) CO 2

3) H 3 O+

  1. Mg (^) Cl OH

O

C

O OH (^) CH 2 C OH

O OH

OH H C O

CH 2 C CH 3 CH 2 CH 2 OH

O CH 3 OH

CH C

O OH

Br CH 3 CH 2 OH C

O OH O N O

  1. Complete the following transformation. Show each intermediate. You do not need to show mechanisms. A.

B. Use a Grignard

CH 3 CH 2 C CH 2 CH 2 OH

O

OH

I

O O

C

O

OH