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Quiz on Amines: Classification, Odors, and Reactions, Quizzes of Organic Chemistry

A quiz on chapter 24 of a chemistry textbook focusing on amines. It includes multiple-choice questions to test understanding of amine classification, odors, and reactions. Questions cover topics such as identifying the type of amine, describing the odor of a specific amine, explaining why lemon juice eliminates the odor of amines in fish, and completing reactions and mechanisms.

Typology: Quizzes

Pre 2010

Uploaded on 08/18/2009

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CH243 Name____________
Quiz Chpt 24 Amines
Due 5/12/2009
Multiple Choice:
___ 1. Classify the amine represented by the following structural formula
A. secondary C. tertiary E. quaternary
B. penitentiary D. primary F. none of these
___ 2. Describe the odor of 1,5-diaminopentane, H2N-CH2CH2CH2CH2CH2-NH2.
A. fingernail polish remover
B. skunk
C. vinegar
D. roses
E. decaying animal tissue
F. none of these
___ 3. The unpleasant odor that cooked fish sometimes has is due to the presence of amines. Sprinkling
lemon juice, which contains citric acid, on the fish eliminates this odor. Why?
A. Enzymes in the lemon juice break down proteins in the fish.
B. The lemon juice squirts in your eye so that you don't notice the odor anymore
C. The citric acid in the lemon juice reacts with the amines, which are bases, producing salts, which
don't have an odor.
D. The water in the lemon juice dilutes the amines.
E. The smell of the citric acid masks the smell of the amines
F. none of these
1. What is the name for the compound represented by the following structural formula?
NCH3
CH3
2. Rank the following compounds in order of decreasing basicity. (#1 is most basic)
NH2
H3CCH3
NH2CH2NH2NH2
CF3
CH3CH2CH
CH3
CH2N
H
CH3
pf3
pf4

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CH243 Name____________ Quiz Chpt 24 Amines Due 5/12/

Multiple Choice:

___ 1. Classify the amine represented by the following structural formula

A. secondary C. tertiary E. quaternary B. penitentiary D. primary F. none of these

___ 2. Describe the odor of 1,5-diaminopentane, H 2 N-CH 2 CH 2 CH 2 CH 2 CH 2 -NH 2. A. fingernail polish remover B. skunk C. vinegar D. roses E. decaying animal tissue F. none of these

___ 3. The unpleasant odor that cooked fish sometimes has is due to the presence of amines. Sprinkling lemon juice, which contains citric acid, on the fish eliminates this odor. Why? A. Enzymes in the lemon juice break down proteins in the fish. B. The lemon juice squirts in your eye so that you don't notice the odor anymore C. The citric acid in the lemon juice reacts with the amines, which are bases, producing salts, which don't have an odor. D. The water in the lemon juice dilutes the amines. E. The smell of the citric acid masks the smell of the amines F. none of these

  1. What is the name for the compound represented by the following structural formula?

N

CH 3

CH 3

  1. Rank the following compounds in order of decreasing basicity. (#1 is most basic)

NH 2

H 3 C (^) CH 3

NH 2 CH 2 NH 2 NH 2

CF 3

CH 3 CH 2 CH

CH 3 CH 2 N

H CH 3

  1. Complete the following reactions:

O

N CH 3

HO

HO

O

N CH 3

CH 3 CO

CH 3 CO

O

Morphine (^) O Heroin

HCl

  1. Outline the tyrosine backbone (indicate all parts that originated from tyrosine) in the structure of morphine above. (1pt)
  2. Complete the missing reagents or products:

CH 3

NO 2

CH 3

NH 2

CH 3

C N

CH 3

CH 2 NH 2

  1. HNO 3 , H 2 SO 4
  2. Cu 2 O, Cu(NO 3 ) 2 , H 2 O
  1. Complete the following reaction showing all intermediates: (3 pts)

N H

CH 3

  1. CH 3 I (excess)
  2. Ag 2 O, H 2 O
  3. heat
  1. Fill in the missing reagents:

NH 2

O

O

OH N

  1. Propose a step by step mechanism for the following biological conversion of dopamine into a precursor of morphine:

CH

O

HO

NH 2

HO

HO

NH

HO

HO

  • H