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Reactions, mechanisms, compounds and other data divided into 4 chapters for organic chemistry 2 course
Typology: Cheat Sheet
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- April 2, Andrew Rosen
1.6.1 Hemiacetals
(^2) The protonated carbonyl compound is called an oxonium cation and is highly reactive toward nucleophilic attack
1.6.3 Cyclic Acetals
1.6.4 Thioacetals
Imine Formation
Enamine Formation
(^3) Note that this mechanism is dierent than what the textbook provides
Reacting the 1 ◦^ or 2 ◦^ alkyl halide with :P(C 6 H 5 ) 3 will cause the halide to be replaced by P+(C 6 H 5 ) 3 Using RLi will take o the hydrogen of the attached carbon of the alkane and give it a -1 charge due to the new electron pair
2.5.1 Esterication
Fischer esterications are acid-catalyzed
2.5.2 Saponication
2.5.3 Lactones
2.6.1 Amides from Acyl Chlorides
2.6.2 Amides from Carboxylic Anhydrides
2.6.6 Nitriles from the Dehydration of Amides
2.6.7 Hydrolysis of Nitriles
2.6.8 Lactams
These alkyl chloroformates can react with ammonia or amines to form carbamates (urethanes)
3.3.2 Halogenation at the α Carbon
3.3.3 The Haloform Reaction
Use of hydroxide or an alkoxide will form this This enolate is known as the thermodynamic enolate
Use of LDA in THF or DME will form this This enolate is known as the kinetic enolate