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6.70. Employing the uncertainty principle, estimate the mini- mum kinetic energy of an electron confined within a region whose size is 1 = 0.20 nm. 6.71. An electron with kinetic energy T 4 eV is confined within a region whose linear dimension is 1 = 1 μm. Using the uncertainty principle, evaluate the relative uncertainty of its velo- city. 6.72. An electron is located in a unidimensional square potential well with infinitely high walls. The width of the well is 1. From the uncertainty principle estimate the force with which the electron possessing the minimum permitted energy acts on the walls of the well. 6.73. A particle of mass m moves in a unidimensional potential field U = kx2I2 (harmonic oscillator). Using the uncertainty prin- ciple, evaluate the minimum permitted energy of the particle in that field. 6.74. Making use of the uncertainty principle, evaluate the mini- mum permitted energy of an electron in a hydrogen atom and its corresponding apparent distance from the nucleus. 6.75. A parallel stream of hydrogen atoms with velocity v 600 m/s falls normally on a diaphragm with a narrow slit behind which a screen is placed at a distance 1 = 1.0 m. Using the uncer- tainty principle, evaluate the width of the slit S at which the width of its image on the screen is minimum. 6.76. Find a particular solution of the time-dependent Schrodinger equation for a freely moving particle of mass m. 6.77. A particle in the ground state is located in a unidimensional square potential well of length 1 with absolutely impenetrable walls (0 < x < 1). Find the probability of the particle staying within 1 2 a region - 3 - 1 < x < - 3 -1.
6.78. A particle is located in a unidimensional square potential well with infinitely high walls. The width of the well is 1. Find the normalized wave functions of the stationary states of the particle, taking the midpoint of the well for the origin of the x coordinate. 6.79. Demonstrate that the wave functions of the stationary states of a particle confined in a unidimensional potential well with infi- nitely high walls are orthogonal, i.e. they satisfy the condition
1)7,11)„,• dx = 0 if n' n. Here 1 is the width of the well, n are
integers. 6.80. An electron is located in a unidimensional square potential well with infinitely high walls. The width of the well equal to 1 is such that the energy levels are very dense. Find the density of energy levels dN/dE, i.e. their number per unit energy interval, as a func- tion of E. Calculate dNIdE for E = 1.0 eV if 1 = 1.0 cm. 6.81. A particle of mass m is located in a two-dimensional square potential well with absolutely impenetrable walls. Find:
254
(a) the particle's permitted energy values if the sides of the well are 1, and 12; (b) the energy values of the particle at the first four levels if the well has the shape of a square with side 1. 6.82. A particle is located in a two-dimensional square potential well with absolutely impenetrable walls (0 < x < a, 0 < y < b). Find the probability of the particle with the lowest energy to be located within a region 0 < x < a/3. 6.83. A particle of mass m is located in a three-dimensional cubic potential well with absolutely impenetrable walls. The side of the cube is equal to a. Find: (a) the proper values of energy of the particle; (b) the energy difference between the third and fourth levels; (c) the energy of the sixth level and the number of states (the degree of degeneracy) corresponding to that level. 6.84. Using the Schrodinger equation, demonstrate that at the point where the potential energy U (x) of a particle has a finite discontinuity, the wave function remains smooth, i.e. its first deriva- tive with respect to the coordinate is continuous. 6.85. A particle of mass m is located in a unidimensional potential field U (x) whose shape is shown in Fig. 6.2, where U (0) = 00. Find:
Fig. 6.2.
(a) the equation defining the possible values of energy of the particle in the region E < U0; reduce that equation to the form
sin kl = ±k1 Vh2/2ml2 Uo,
where k =1/-2mElh. Solving this equation by graphical means, demonstrate that the possible values of energy of the particle form a discontinuous spectrum; (b) the minimum value of the quantity 12U0 at which the first energy level appears in the region E < U 0. At what minimum value of /2 U, does the nth level appear?
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6.94. Particles of mass m and energy E^ move from the left to the potential barrier shown in Fig. 6.3. Find: (a) the reflection coefficient R of the barrier for E > U 0; (b) the effective penetration depth of the particles into the region x > 0 for E <^ Uo, i.e. the distance from the barrier boundary to the point at which the probability of finding a particle decreases e-fold.
Fig. 6.3.
6.95. Employing Eq. (6.2e), find the probability D of an electron with energy E tunnelling through a potential barrier of width 1 and height U0provided the barrier is shaped as shown: (a) in Fig. 6.4; (b) in Fig. 6.5.
Fig. 6.4. Fig. 6.5. Fig. 6.6.
6.96. Using Eq. (6.2e), find the probability D of a particle of mass m and energy E tunnelling through the potential barrier shown in Fig. 6.6, where U (x) = U 0(1 — x2112).
6.3. PROPERTIES OF ATOMS. SPECTRA
L = 0, 1, 2, 3, 4, 5, 6,... (L): S, P, D, F, G, H, I, ...
17-
. ===
4
3 Diffuse series
2 Principal series
3 Sharp series
H
K-series
Fig. 6.8.
N
where R^ is the Rydberg constant,^ a is the Rydberg correction. Fig. 6.7 illustrates the diagram of a lithium atom terms.
Li
Fig. 6.7.
(2) for the basic (normal) term J = IL — SI if the subshell is less than half-filled, and J = L S in the remaining cases.
N I gi where g1 and g2are the statistical weights (degeneracies) of the corresponding levels.
(6.3d)
(6.3e)
(6.3f)