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Chemistry Exam 1 Review and Problem Set, Lecture notes of Chemistry

The review and problem set for exam 1 in chemistry, covering topics such as concentration units, nomenclature of organic compounds, functional groups, definitions, and various chemical concepts.

What you will learn

  • Identify functional groups and hybridization of each carbon atom in Retinal (Vitamin A) and Cocaine.
  • How to prepare 0.1M solution of Na2SO4 from given mass?

Typology: Lecture notes

2021/2022

Uploaded on 09/12/2022

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October 3, 2003
Review and Problem set for Exam 1
I. Concentration Units. Explain how you would prepare 200 mL of 0.1M solution of Na2SO4. The molecular
weight of Na2SO4 is 142 g/mol
Need 0.1 moles Na2SO4 per 1L solution, or 0.05 moles per 200 mL.
Since the molar mass is 142 g/mol, 0.05 moles is 2.84 g. So, weight 2.84 g of Na2SO4, transfer to a measuring
cylinder, and add water to make up the total volume of 200 mL.
II Nomenclature of Organic Compounds. Give the IUPAC names for each of the following compounds:
a)
CHCH3
CH3
CH3
1-Isopropyl-2-methylcyclohexane
b)
CH3CH2CHCH3
CH CH2
3-Methyl-1-pentene
c)
CH3
NO2
NO2
O2N
2,4,6-Trinitrotoluene
pf3

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October 3, 2003 Review and Problem set for Exam 1

I. Concentration Units. Explain how you would prepare 200 mL of 0.1M solution of Na 2 SO4. The molecular weight of Na 2 SO 4 is 142 g/mol

Need 0.1 moles Na (^) 2SO 4 per 1L solution, or 0.05 moles per 200 mL. Since the molar mass is 142 g/mol, 0.05 moles is 2.84 g. So, weight 2.84 g of Na 2 SO4, transfer to a measuring cylinder, and add water to make up the total volume of 200 mL.

II Nomenclature of Organic Compounds. Give the IUPAC names for each of the following compounds:

a)

CHCH 3

CH 3

CH 3

1-Isopropyl-2-methylcyclohexane

b)

CH 3 CH 2 CHCH (^3)

HC CH (^2)

3-Methyl-1-pentene

c) CH 3 NO (^2)

NO (^2)

O 2 N

2,4,6-Trinitrotoluene

III. Functional Groups. Identify the functional groups in the following molecules, and give the hybridization of each carbon atom:

a)

H 3 C CH 3

CH 3

CH 3 CH 3 O

H

Retinal (Vitamin A)

Carbonyl group; C-C double bonds. For CH 3 groups- sp^3 ; four carbons in the ring not connected by double bond- sp 3 ; remaining carbons in the molecule- sp^2.

b)

CH 3

NCH 3

O O

O

O Cocaine

Amino (NCH3); two ester groups; phenyl group. Ester and phenyl carbons- sp^2 ; CH3- sp 3 ; all carbons in the seven-membered ring- sp 3