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Solutions to homework problems in physics 275, covering topics such as the aufbau principle, magnetic fields, and hund's rules. Learn about the behavior of electrons in atoms and their energy levels under various conditions.
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PHYS 275: Hw 8 Solutions Chapter 9 : 5 - ) Remembering the Aufbau principle, we see that 113 electrons would require the 7p level with one electron. Thus Such an element might not exist because the proton-proton electromagnetic repulsion would overcome the nucleon-nucleon strong interaction. This is because the strong force is about 100 times stronger than the electromagnetic force but has a limited range of action. 20 - ) Under a weak magnetic field the state would be split with. Thus to determine how many states one would get we need to know how many different would occur, which is states! In a sketch: 21 - ) Under a strong magnetic field the state would be split with. Thus we need to determine how many different values would take. For
. Thus, That means 5 levels! where 27 - ) Hund’s Rules help us determine the angular momentum quantum numbers of the ground state of atoms. (a) For which gives a spin angular momentum of , thus there will be states for carbon, called triplet states.
For which gives a spin angular momentum of , thus there will be states for nitrogen, called quadruplet states. (b) For which gives a spin angular momentum of , thus there will be states for iron, called pentaplet states. Not that there is also a third rule to the Hund’s rules. It states that a minimum will have the lowest energy when the sub-shell is less than half filled. Otherwise a maximum will have the lowest energy. In general, the ground state term symbol is , and this is how the angular momentum states of multi- electron atoms are represented. In the case of carbon that would mean. Chapter 10 : 14 - ) For 18 - ) For This is about 10 times more powerful than the ordinary springs we use in the labs. 25 - ) CO absorbs radiation at. This means This energy value corresponds to the rotational transitions. To find exactly which rotational transition, we recall where from Table 10-1, and from problem 18. Suppose a transition occurs from state. The energy difference would be