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Exam 2 Questions for Organic Chemistry | CHEM 343, Exams of Organic Chemistry

University of Wisconsin (UW) - MilwaukeeOrganic Chemistry

Material Type: Exam; Class: Organic Chemistry; Subject: Chemistry; University: University of Wisconsin - Milwaukee; Term: Spring 1999;

Typology: Exams

Pre 2010

Uploaded on 09/02/2009

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Last Name ___________________________________ First Name _________________________________
Please Print. Please put your name on the back of the test also.
ORGANIC CHEMISTRY 343
Schwabacher
March 24, 1999
EXAM 2
page 1. (36 points) _____________________
page 2. (18 points) _____________________
page 3. (30 points) _____________________
page 4. (20 points) _____________________
TOTAL (104 points)________________________
Quiz scores so far: _____________ Q3
_____________ Q4
____________ Q5
There are 5 pages to this exam, including this cover page. Check to be sure yours is complete.
pf3
pf4
pf5

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Download Exam 2 Questions for Organic Chemistry | CHEM 343 and more Exams Organic Chemistry in PDF only on Docsity!

Last Name ___________________________________ First Name _________________________________

Please Print. Please put your name on the back of the test also.

ORGANIC CHEMISTRY 343

Schwabacher

March 24, 1999

EXAM 2

page 1. (36 points) _____________________

page 2. (18 points) _____________________

page 3. (30 points) _____________________

page 4. (20 points) _____________________

TOTAL (104 points)________________________

Quiz scores so far: _____________ Q

_____________ Q

____________ Q

There are 5 pages to this exam, including this cover page. Check to be sure yours is complete.

I. (18 points) Nomenclature: Provide the name for given structure, or structure for given name. Don't forget

stereochemistry! (E, Z, R, S)

A) H

H 3 C

B) C

CH 3

H 2 C CH 3

H C^ C

H 3 C

H

H

C)

D) C C^ C^ CH^3

F

H

H 3 CCH 2

E) (S)-2,3,4-trimethyl-1-pentene

F) meso -3,4-dibromohexane

II. (18 points) Fill in the boxes with R, S, E, or Z to specify stereochemistry.

a)

Br (^) Cl H H

b)

Cl Cl H H

c)

Br ClH

H

d)

Br (^) Cl H H

e)

H Cl

f)

H^ Cl

Find among the molecules above, and identify by letters (a-f)

A pair of enantiomers. ________

A pair of diastereomers. ________

A meso molecule. ________

IV. (30 points) Provide products, showing stereochemistry where relevant.

A. HgS O 4

H 2 O

H 2 SO 4

B.

Br 2

H 2 O

C. Show stereochemistry for this one!

1 ) BH 3 / THF

  1. H 2 O 2 NaOH

CH 3

H

D. +^ H^2

Pd

E.

Li / NH 3

F. +^ CHCl^3

KOH

V. (20 points) Complete these equations to show reasonable reactions by providing starting materials, reagents, or

both. A reaction that produces only the given product is preferred over a reaction that produces a mixture

of products.

A.

B.

O

H O

C.

D. Br