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Ethanol CDA 19 200 Proof
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Trade name (^) Ethanol CDA 19 200 Proof Synonyms (^) Denatured Alcohol Use Industrial use, Raw material for chemical processes, Raw material for industry, Solvent Company Sasol Chemicals (USA) LLC (an affiliate of Sasol Chemicals North America LLC) Address 12120 Wickchester Lane Houston TX 77079 Telephone CHEMTREC North America Transportation Emergency (24-hr) (800) 424- 9300 CHEMTREC World Wide (703) 527- 3887 Other Emergencies (24-hr) (337) 494- 5142 MSDS and Product Information (8:00am-4:30pm CST) (281) 588- 3491 Health and Safety Information (7:30am-4:00pm CST) (281) 588- 3492 E-mail address SasolElectronicSDS@us.sasol.com
SECTION 2 HAZARDS IDENTIFICATION
GHS Hazards Flammable liquids Category 2 Eye irritation Category 2A Acute toxicity (Inhalation) Category 4 Carcinogenicity Category 2
Hazard symbols
Signal word Danger
Hazard statements H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H332 Harmful if inhaled. H351 Suspected of causing cancer.
Precautionary statements
Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
LABEL ELEMENTS
Ethanol CDA 19 200 Proof
P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ eye protection/ face protection. P264 Wash skin thoroughly after handling. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use only outdoors or in a well-ventilated area. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood.
Response P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P370 + P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide for extinction. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Storage P403 + P405 + P235 Store locked up in a well-ventilated place. Keep cool.
Disposal P501 Dispose of contents/ container to an approved waste disposal plant.
SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Weight percent Ethanol 64-17-5 95 Methyl isobutyl ketone 108-10-1 4 Heptane 142-82-5 1
See Section 8 for Exposure Guidelines and Section 15 for Regulatory Classifications.
SECTION 4 FIRST AID MEASURES
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. When symptoms persist or in all cases of doubt seek medical advice. Wash contaminated clothing before re-use.
Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. In case of shortness of breath, give oxygen. Call a physician immediately.
Ethanol CDA 19 200 Proof
Inhalation Respiratory protection is normally not required except in emergencies or when conditions cause excessive airborne levels of mists or vapors. Use NIOSH approved respiratory protection.
EXPOSURE GUIDELINES
Components Exposure limit(s) Ethanol ACGIH STEL 1,000 ppm OSHA PEL 1,000 ppm 1,900 mg/m
Methyl isobutyl ketone
OSHA PEL 100 ppm 410 mg/m ACGIH TLV (8-hour) 20 ppm ACGIH STEL 75 ppm
Heptane OSHA PEL 500 ppm 2,000 mg/m ACGIH TLV (8-hour) 400 ppm 1,640 mg/m ACGIH STEL 500 ppm 2,050 mg/m NIOSH Ceiling 440 ppm 1,800 mg/m
PEL= Permissible Exposure Limits TWA= Time Weighted Average (8 hr.) TLV= Threshold Limit Value STEL= Short Term Exposure Limit (15 min.) EL= Excursion Limit WEEL= Workplace Environmental Exposure Level
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance liquid;
Colour Clear, colorless
Form liquid
Odour alcohol-like
Odour Threshold no data available
Flash point 13 °C, 55 °F;
Flammability Upper explosion limit: 20.0 %(V)
Lower explosion limit: 4.0 %(V)
Boiling point/boiling range
74 - 80 °C, 165.2 - 176 °F;
Melting point/range ca. - 114 °C, - 173 °F;
Auto-ignition temperature
ca. 400 °C, 752 °F;
Decomposition temperature
no data available
Ethanol CDA 19 200 Proof
Flammability (solid, gas)
no data available
Vapour pressure ca. 66.661 hPa @ 20 °C, 68 °F;
Vapour density ca. 1.
Density 0.79 g/cm3 @ 15.5 °C, 60 °F;
Specific gravity no data available
Water solubility completely miscible
Viscosity no data available
pH (^) no data available
Evaporation rate no data available
Partition coefficient: n- octanol/water
no data available
SECTION 10 STABILITY AND REACTIVITY
Reactivity Stable at normal ambient temperature and pressure.
Chemical stability No decomposition if stored and applied as directed.
Conditions to avoid Keep away from heat and sources of ignition.
Hazardous decomposition products
Combustion products include carbon dioxide, carbon monoxide and possibly other unidentified organic compounds.
Materials to avoid Can react with strong oxidizers, inorganic acids, and halogens.
Hazardous polymerisation
None.
SECTION 11 TOXICOLOGICAL INFORMATION
Acute dermal toxicity LD50 Rabbit: > 2,000 mg/kg; OECD Test Guideline 402 Test substance: Ethanol; (literature value)
LD50 Rabbit: > 2,000 mg/kg Test substance: MIBK; (literature value)
LD50: > 2,000 mg/kg Test substance: Heptane
Acute inhalation LC50 Mouse (4 hours): > 20 mg/l
Ethanol CDA 19 200 Proof
System: Salmonella typhimurium; with and without metabolic activation Result: In vitro tests did not show mutagenic effects Test substance: MIBK (literature value) Result: In vitro tests did not show mutagenic effects Test substance: Heptane
Genotoxicity in vivo : no data available
Assessment Mutagenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity Reproductive toxicity: male and female Rat; Inhalation; OECD Test Guideline 416 NOAEL (parents): 3,000 mg/kg NOAEL (F1): 3,000 mg/kg NOAEL (F2): 3,000 mg/kg Test substance: Heptane no data available
Assessment Reproductive toxicity: Based on available data, the classification criteria are not met.
Teratogenicity: Mouse; OECD Test Guideline 414 NOAEL (teratogen): 3,000 mg/kg NOAEL (maternal): 900 mg/kg Test substance: Heptane Rat; OECD Test Guideline 414 NOAEL (teratogen): 9,000 mg/kg NOAEL (maternal): 3,000 mg/kg Test substance: Heptane
Assessment teratogenicity: Based on available data, the classification criteria are not met.
STOT - single exposure
no data available
STOT - repeated exposure
Rat; Oral; 90 - day; NOAEL: 1,730 mg/kg LOAEL: 3,160 mg/kg Test substance: Ethanol Based on available data, the classification criteria are not met.
Aspiration toxicity no data available
Carcinogenicity Assessment carcinogenicity: Suspected of causing cancer.
Carcinogenicity ratings
Methyl isobutyl ketone
Ethanol CDA 19 200 Proof
IARC Group 2B: Possibly carcinogenic to humans
SECTION 12 ECOLOGICAL INFORMATION
Toxicity to fish LC50 (Pimephales promelas (fathead minnow)) 96 hours: > 100 mg/l; flow-through test Test substance: Ethanol (literature value)
LC50 (Danio rerio (zebra fish)) 96 hours: > 100 mg/l; static test Test substance: MIBK (literature value)
Toxicity to aquatic invertebrates
EC50 (Ceriodaphnia dubia (water flea)) 48 hours: > 100 mg/l; static test Test substance: Ethanol (literature value)
EC50 (Daphnia magna (Water flea)) 48 hours: > 100 mg/l; static test Test substance: MIBK (literature value)
Toxicity to algae (^) EC50 (Chlorella vulgaris) 72 hours: > 100 mg/l; static test; OECD Test Guideline 201 Test substance: Ethanol (literature value)
Chronic toxicity to aquatic invertebrates
NOEC (Ceriodaphnia dubia (water flea)) 10 d: 9.6 mg/l; semi-static test Test substance: Ethanol (literature value)
NOEC (Daphnia magna (Water flea)) 21 d: > 10 - 100 mg/l; semi-static test; OECD Test Guideline 211 Test substance: MIBK (literature value)
Biodegradation Readily biodegradable
OECD Test Guideline 301B (28 d): > 60 % Test substance: Ethanol (literature value)
OECD Test Guideline 301F (28 d): > 60 % Test substance: MIBK (literature value)
Bioaccumulation Test substance: Ethanol No bioaccumulation is to be expected (log Pow <= 4).
Test substance: MIBK No bioaccumulation is to be expected (log Pow <= 4).
Mobility in soil no data available
Other adverse effects no data available
Ethanol CDA 19 200 Proof
SARA 302 Status Components CAS-No. Weight percent No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 311/312 Classification "Fire hazard", "Immediate (acute) health hazard", "Delayed (chronic) health hazard"
SARA 313 Chemical Components CAS-No. Weight percent 2 - Pentanone, 4-methyl- 108 - 10 - 1 4 %
US. EPA CERCLA Hazardous Substances (40 CFR 302) Components Reportable Quantity Weight percent 2 - Pentanone, 4-methyl- 5,000 LB 4 %
INTERNATIONAL REGULATIONS
WHMIS Classification Class B, Division 2: Flammable liquid. Class D, Division 2, Subdivision A: Very toxic material Class D, Division 2, Subdivision B: Toxic material.
European Union Classification according to Regulation (EU) 1272/2008.
Flammable liquids, Category 2 Eye irritation, Category 2 Acute toxicity (Inhalation), Category 4 Carcinogenicity, Category 2
Australia. Inventory of Chemical Substances (AICS) (^) Listed
Japan. Inventory of Existing and New Chemical Substances (ENCS) Listed
Japan. Industrial Safety & Health Law (ISHL) Inventory Listed
Canada. Domestic Substances List (DSL) Inventory (^) Listed
Canadian Non-Domestic Substance Listing (NDSL) Not listed
European Inventory of Existing Commercial Chemical Substances (EINECS) Listing
Listed
Philippines. Inventory of Chemicals / Chemical Substances (PICCS) (^) Listed
Korea. Existing Chemicals Inventory (KECI) (^) Listed
China. Inventory of Existing Chemical Substances (IECSC) (^) Listed
Mexico. National Inventory of Chemical Substances (INSQ) (^) Listed
New Zealand. Inventory of Chemicals (NZIoC) (^) Listed
Ethanol CDA 19 200 Proof
Switzerland. Inventory of Notified New Substances (CHINV) Listed
Taiwan. National Existing Chemical Inventory (NECI) Listed
Please note: The names and CAS numbers which are used for this product in the stated inventories may deviate from the information which is listed in Section 3.
STATE REGULATIONS
California Prop. 65 Components CAS-No. 2 - Pentanone, 4-methyl- 108 - 10 - 1
SECTION 16 OTHER INFORMATION
HAZARD RATINGS
Health Flammability
Physical Hazard/ Instability HMIS® 2 3 0 NFPA 2 3 0
THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL PURPOSES
ONLY, UPON THE EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN ASSESSMENT OF
APPROPRIATE USE AND APPROPRIATE SHIPPING, TRANSFER AND STORAGE MATERIALS AND PROCEDURES
FOR SASOL CHEMICALS (USA) LLC'S PRODUCTS. ALTHOUGH BASED ON INFORMATION SOURCES WHICH
SASOL CHEMICALS (USA) LLC CONSIDERS ACCURATE AND RELIABLE, SASOL CHEMICALS (USA) LLC MAKES
NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING ANY WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE, REGARDING THE VALIDITY OF THIS INFORMATION, THE INFORMATION
SOURCES UPON WHICH THE SAME ARE BASED, OR THE RESULTS TO BE OBTAINED, AND EXPRESSLY
DISCLAIMS LIABILITIES FOR DAMAGES OR INJURIES RESULTING FROM THE USE THEREOF.
