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The damage caused by salts in building materials, particularly in mortar, and the research being conducted to find suitable crystallization inhibitors for sodium chloride and sodium sulfate. The document also touches upon the importance of understanding salt damage in the context of planetary core formation.
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Page 3 Inside Materials - Newsletter Delft Centre for Materials - November 2013
By Sanne Granneman, Barbara Lubelli, and Rob P.J. van Hees Architectural Engineering and Technology, A&BE, TU Delft
The weathering of porous materi- als due to the presence of salts has been known since antiquity. However, serious studies and investigations were not conducted until the 19th century. One of the fields of interest includes historic masonry, where salt damage can affect natural stone, brick and mortar (see Figure 1). Mortars are building materials, which are for example used in masonry, as the bonding material in between bricks or stones or as a plaster or render. Because of its pore size distribution (with both coarse as fine pores) and its relatively low mechanical strength, mortar is one of the building materials most affected by salt crystalliza- tion damage. As a consequence, replacement of plasters, ren- ders and pointing mortars often constitutes a large part of total restoration costs. Salts present in masonry can originate, amongst others, from sea salt spray, rising damp, road salt, salt storage and the building materials itself.
The damage caused by salt crystalliza- tion is closely related to the location of crystallization. Crystallization at the
Figure 1. Salt damage in plaster (Church in de Rijp, the Netherlands) and pointing mortar (building in Oostkapelle, the Netherlands)
be added to a fresh mortar, which can subsequently be used for restoration or renovation. Then, when salts penetrate the materials, they will cause less or no damage at all.
Amongst the most damaging salts for building materials are sodium chlo- ride and sodium sulfate. The initial phase of the research was directed towards finding suitable modifiers for these salts. Sodium chloride is a salt, which has been already extensively researched and one of the effective modifiers, that has been identified is sodium ferrocyanide. This molecule not only inhibits the growth of sodium chloride but also modifies the crystal habit from cubic to dendritic. Previous laboratory tests show that instead of forming a layer with cubic shaped crys- tals, the sodium chloride crystals form feather-like crystals, which only poorly adhere to the pore surface (see Figure
The research currently carried out >>
surface of a material (efflorescence) is relatively harmless. However, crystal- lization inside the material (crypto- or sub-florescence) can lead to severe damage. The damage is attributed to crystallization pressure. When a crystal grows in a confined space such as a pore, it will eventually have no more room to grow. However, usually there is still salt in solution present. When water from this solution evaporates, a supersaturated solution will form. The combination of crystal and super- saturated solution results in a pres- sure against the pore wall. Eventually the pressure overcomes the tensile strength of the material and cracking and crumbling will occur [1].
Even though much research has been undertaken, no definitive solution to prevent salt crystallization damage has been found yet. Recently research has started to examine the use of crystalli- zation modifiers. These molecules alter the crystallization behaviour. They can prevent or delay nucleation (inhibi- tors), promote nucleation (promoter) and/or adsorb onto specific crystal fac- es, thereby changing the crystal mor- phology (habit modifier). The positive effects of modifying the crystallization behaviour can be lowering the super- saturation, or promoting the formation of efflorescences instead of crypto- florescences [1,2]. One of the aims of the PhD research of the first author is to develop a better salt resistant repair mortar, which already contains an inhibitor. The molecules will have to
Inside Materials - Newsletter Delft Centre for Materials - November 2013 Page 4
As we all know, the DCMat research often attracts international attention because of its quality and innovative features. Very recently BBC radio 4 did send a reporting team to Delft to make a 30 minutes documentary about the latest developments in Self Healing Materials and the leading position DCMat plays in this international field. In the documentary our work on self-healing asphalt, concrete, polymers, coatings, ceramics, metals, catalysts and interfaces will be presented. The program will be broadcasted in November on BBC 4 and at a slightly later stage on BBC world. The link to the documentary will be placed on the DCMat website as soon as it is available.
The largest differentiation event in Earth and other terrestrial planets was the process of early metal core segregation from a silicate mantle. As movement of molten metal generates a magnetic field that helps life on Earth to survive cosmic radiation, the study of core formation contributes to our understanding of the context of the origin of life on Earth and possibly elsewhere in the Solar System (fig.1). Studying core formation scenarios in terrestrial planetary bodies was topic of the PhD thesis of Josepha Kempl, who recently joined the Department of Environment and Materials, CEG as a post-doctoral researcher to study inorganic self-healing mechanisms in building materials.
Investigating planetary interiors is
nowadays experimentally performed at high pressure and high temperature (HPT) conditions. For the experimental set-up, HPT resistant materials are applied in machines such as e.g. multi-anvil presses. Sample materials, simulating rock compositions of the deep Earth are filled into noble metal capsules and exposed to temperatures of up to 2300˚C and pressures of more than 25 GPa in a Tungsten-Carbide cubic assembly (fig.2). This equals Earth’s depths of ca. 750 km and more.
The experimental set-up chosen in Josepha’s thesis simulated the segregation of a silicon bearing molten iron metal alloy from a silicate melt between 9 and 15 GPa and 1800 - 2300˚C (fig.3). Samples were
(e.g. complex formation, adsorption on calcite). In a later stage, the effect of the addition of modifiers on the work- ability of a fresh mortar, and on the hygric and mechanical properties of a hardened mortar will be studied.
References:
in this project focuses on the inter- action of modifiers with the crystal surface, aiming at gaining in-depth knowledge on the influence of modi- fiers on the crystal growth and the crystallization damage. This process is studied by means of molecular modelling and laboratory experiments. Furthermore, bulk crystallization tests will be performed in order to study the influence of concentration and pH on the effectiveness of the modifiers and the possible interaction between lime mortar components and inhibitor
Figure 2. Images showing the effect of so- dium ferrocyanide on NaCl growth. Inhibitor added to the salt solution. (A) SEM picture of a cross-section showing non-cubic crystallization in a pore, 10000x magnifica- tion. (B) SEM picture showing crystallization at the surface of a porous material, 500x magnification. (C) Macroscale picture of dendritic, feather-like crystallization at the surface of a brick
investigated by electron microprobe (EPMA) and multi collector (MC) inductively coupled plasma mass spectrometry (ICP-MS), to determine Si element partitioning and Si >>