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Temperature of solution ____25.0____ OC Corresponding Nernst Constant ___59.2_____ Calculated value of k ____466.31____ Calculated Eref electrode ___332.7____ Experimental Data Condition Total Volume Equilibrium Molarity of Ligand Ecell(mV) “Y” Log[NH 3 ] Start 100 mL
Cl-^ added 110 mL
NH 3 added 120 mL 0.0439 M - 25.6 4.
NH 3 added 130 mL 0.0810 M - 64.7 4.
NH 3 added 140 mL 0.1129 M - 85.1 5.
I-^ added 150 mL
Calculated Molarity of Stock NH 3 __0.527 M_____ Calculated Constants Ksp for AgCl 2.2810^- 10 Kf for Ag(NH 3 )+p 2.0110^7 p for Ag(NH 3 )+p 2.30 (~2) Ksp for AgI 1.97*10^- 16 EO^ for AgCl 228 mV EO^ for Ag(NH 3 )+p 367 mV EO^ for AgI - 130 mv