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Chemical Formulas and Nomenclature: A Comprehensive Guide, Slides of Chemistry

chemical formula, name is prefixed by number of atoms present. CO: carbon monoxide. SiO. 2. : silicon dioxide. NI. 3. : nitrogen triiodide.

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2021/2022

Uploaded on 09/12/2022

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Chemical Formulas
A chemical formula gives the numbers
and types of atoms that are found in a
substance.
When the substance is a discrete
molecule, then the chemical formula is
also its molecular formula.
Fe (iron) is a chemical formula
Fe2O3 is a molecular formula
pf3
pf4
pf5
pf8
pf9
pfa
pfd
pfe
pff
pf12
pf13
pf14
pf15
pf16
pf17
pf18
pf19
pf1a
pf1b
pf1c
pf1d
pf1e
pf1f
pf20
pf21
pf22
pf23
pf24
pf25
pf26

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Chemical Formulas

 A chemical formula gives the numbers and types of atoms that are found in a substance.  When the substance is a discrete molecule, then the chemical formula is also its molecular formula. Fe (iron) is a chemical formula Fe 2

O

3 is a molecular formula

The Elements

 The chemical formulas of most of the elements are simply their elemental symbol: Na (sodium) Fe (iron) He (helium) U (uranium)  These chemical formulas are said to be monatomic—only an atom in chemical formula

Binary Compounds

 A binary compound is one composed of only two different types of atoms. Rules for binary compound formulas

  1. Element to left in Periodic Table comes first except for hydrogen: KCl PCl 3 Al 2

S

3 Fe 3

O

4

Binary Compounds

  1. Hydrogen comes last unless other element is from group 16 or 17: LiH, NH 3

, B

2

H

4

, CH

4

  1. If both elements are from the same group, the lower element comes first: SiC, BrF 3

Other Compounds

 However, the preceding rule is often ignored when writing organic formulas (molecules containing carbon, hydrogen, and maybe other elements) in order to give a better idea of how the atoms are connected: C 2

H

6 O is the molecular formula for ethanol, but nobody ever writes it this way—instead the formula is written C 2

H

5 OH to indicate one H atom is connected to the O atom.

Structural Formulas

 Very often, chemists use structural formulas to show where the atoms in a molecule are positioned. The atoms are connected to each other with bonds.  Bonds represent the attractive forces that hold molecules together.  There are three types of structural formulas: line structures, ball-and-stick models, and spacing-filling models.

Line Structures

 For organic molecules, the carbon atoms are often not shown.  C-H bonds are also omitted in line structures.

Line Structures

Space-Filling Models

 Atoms are represent by balls that are color-coded and are approximately the correct relative size of the atoms.  This gives a better perspective of the space available in a molecule.

Comparison of Structural Models

Nonmetallic Binary Compounds

  1. Element that appears first retains its elemental name.
  2. Second element begins with root derived from name and ends with - ide As: arsenide Br: bromide C: carbide Cl: chloride O: oxide F: fluoride H: hydride I: iodide N: nitride S: sulfide

Nonmetallic Binary Compounds

  1. When more than one atom appears in chemical formula, name is prefixed by number of atoms present CO: carbon monoxide SiO 2 : silicon dioxide NI 3 : nitrogen triiodide CCl 4 : carbon tetrachloride PCl 5 : phosphorous pentachloride SF 6 : sulfur hexafluoride IF 7 : iodine heptafluoride

Binary Compounds with Hydrogen

 When hydrogen combines with elements from groups 1 or 17, a diatomic molecule results.  The molecule is named according to the previous rules for nonmetallic binary compounds: NaH: sodium hydride HCl: hydrogen chloride LiH: lithium hydride

Binary Compounds with Hydrogen

 When hydrogen combines with elements from groups 2 or 16, the resulting molecule contains 2 H atoms.  The molecule is named according to the previous rules for nonmetallic binary compounds, but the di is omitted: H 2 S: hydrogen sulfide CaH 2 : calcium hydride  Exception is oxygen: H 2 O: water H 2 O 2 : hydrogen peroxide