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HO: +
H C Br H H
C
H
H H
HO Br
H HO C H H
δ− δ− + Br
Energy
reaction coordinate: progress of reaction
reactants products
transition state: highest energy structure between reactants and products, with fleeting existence. Eact
∆ G (^) rxn
6-
Equilbrium: How complete?
Kinetics: How fast?
governed by ∆ Grxn = -RTlnKeq = ∆ Hrxn - T ∆ Srxn ∆ Grxn < 0 favors formation of products
governed by Eact, where rxn rate α e -Eact/RT smaller Eact or higher temp leads to faster rxn for a reaction with more than one step, the overall rate of reaction depends on the step with the largest Eact, the rate determining step
Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
Copyright 2012 John Wiley & Sons, Inc. (^) Klein, Organic Chemistry
M6Q1: Which are the kinetic products in the energy diagram below, and which are the thermodynamic products?
a. C+D are thermodynamic, E+F are kinetic b. C+D are kinetic, E+F are thermodynamic c. C+D are thermodynamic and kinetic d. E+F are thermodynamic and kinetic