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Material Type: Exam; Professor: Forman; Class: Organic Chemistry I; Subject: Chemistry; University: Saint Joseph's University; Term: Fall 1997;
Typology: Exams
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H 3 CC C Br CH 2 CH 3
CH (^3) CCHCH^32 C CH H 3 C CH 3
b.) Which alkene is most stable? Why? (4 points).
c.) Which of the following predicts that in electrophilic addition of HX to alkenes, the H adds to thecarbon already possessing the greater number of hydrogens? I. Markovnikov’s Rule II. Hammond Postulate III. Cahn-Ingold-Prelog Rules IV. Simmons-Smith d.) Which of the following is the strongest acid? I. CH 3 CH 3 II. CH 2 =CH 2 III. CH=CH IV. CH 4 e.) Which of the following radicals is the most stable? I. II. III. IV.
*c.) (^) CH 3 CH 3
H 2 , Pd
d.) (^) 1. Hg(OAc) 2 , H 2 O, THF CH 3 CH 2 CH=CH (^2) 2. NaBH 4 e.) CH 3 CH 2 C C H^ 1. HBSia2. H 2 O 2 , HO-^2 , THF f.) HH 33 CC^ C^ CHCH^3 1. O^ 2. Zn, AcOH^3 g.) CH C C H 3 CH 2 2 H-Cl h.) 1. BH