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5 Solved Questions on Organic Chemistry II - Assignment 2 | CHEM 332, Assignments of Chemistry

Iowa State University (ISU)Chemistry

Material Type: Assignment; Class: ORGANIC CHEMSTRY II; Subject: CHEMISTRY; University: Iowa State University; Term: Spring 2009;

Typology: Assignments

Pre 2010

Uploaded on 09/02/2009

koofers-user-91q 🇺🇸

10 documents

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1.Circlethemostacidiccompoundandunderlinetheleastacidiccompound.



2.Nomenclature:



3.Predictthemajorproductsforthefollowingreactions.

OCH3

O1.BrMg-CH3

2.H3O+PCC

NaBH4

LiAlH4,

H3O+

1.PhMgBr

2.H2O

3.H2SO4,H

2O,

Heat

1. Hg(OAc)2

2. NaBH4,

NaOH

1. BH3

2. H2O2,NaOH

3. PCC

No Reaction

Ph 

Partial preview of the text

Download 5 Solved Questions on Organic Chemistry II - Assignment 2 | CHEM 332 and more Assignments Chemistry in PDF only on Docsity!

1. Circle the most acidic compound and underline the least acidic compound.

2. Nomenclature:

3. Predict the major products for the following reactions.

OCH 3

O

1.BrMg-CH 3 2.H 3 O+

PCC

A.

B. O

OH

O

NaBH 4

LiAlH 4 , H 3 O+

C. H H

H

O

D.

E.

F.

1.PhMgBr 2.H 2 O 3.H 2 SO 4 , H 2 O, Heat

Hg(OAc) 2
NaBH 4 , NaOH

1. BH 3

H 2 O 2 , NaOH
PCC

OH

No Reaction

OH

H

OH

H

OH

H H

O

4. Draw a step‐by‐step mechanism, including all important resonance structures.

OH

H 3 O+

O

AlCl 3

O

H-OH 2

OH 2 +

H

H OH 2

O (^) + AlCl 3

O+

O

AlCl 4 -

O

H

Cl-AlCl 3 -