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33 Multi Goal Choice of General Chemistry - Final Exam | CH 121, Exams of Chemistry

Material Type: Exam; Class: GENERAL CHEMISTRY; Subject: Chemistry; University: Oregon State University; Term: Winter 2008;

Typology: Exams

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Chemistry 122 Winter 2008 Oregon State University
Final Exam March 17, 2008 Dr. Richard Nafshun
Instructions: You should have with you several number two pencils, an eraser, your 3" x 5" note card, a
calculator, and your University ID Card. If you have notes with you, place them in a sealed backpack
and place the backpack OUT OF SIGHT or place the notes directly on the table at the front of the room.
Fill in the front page of the Scantron answer sheet with your last name, first name, middle initial, and
student identification number. Leave the class section number and the test form number blank.
This exam consists of 33 multiple-choice questions. Each question has four points associated with it
(Question 33 has two). Select the best multiple-choice answer by filling in the corresponding circle on
the rear page of the answer sheet. If you have any questions before the exam, please ask. If you have
any questions during the exam, please ask the proctor. Open and start this exam when instructed. When
finished, place your Scantron form in the appropriate stack and present your University ID Card to the
proctor. You may keep the exam packet, so please show your work and mark the answers you selected
on it.
R = 0.0821 L•atm/mol•K 760 mm Hg = 760 torr = 1 atm m = mol/kg
M = mol/L ΔTTf = imkfΔTTb = imkb
ΠV = nRTV = nRT kf (H2O) = 1.86 ºC/m kb(H2O) = 0.512 ºC/m
kt
A
A
o
]ln[
RT
Ea
Aek
Ka (CH3COOH) = 1.8 x 10-5
SC: 2r = s BCC: 4r = s√3 FCC: 4r = s√2
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Chemistry 122 Winter 2008 Oregon State University Final Exam March 17, 2008 Dr. Richard Nafshun Instructions: You should have with you several number two pencils, an eraser, your 3" x 5" note card, a calculator, and your University ID Card. If you have notes with you, place them in a sealed backpack and place the backpack OUT OF SIGHT or place the notes directly on the table at the front of the room. Fill in the front page of the Scantron answer sheet with your last name, first name, middle initial, and student identification number. Leave the class section number and the test form number blank. This exam consists of 33 multiple-choice questions. Each question has four points associated with it (Question 33 has two). Select the best multiple-choice answer by filling in the corresponding circle on the rear page of the answer sheet. If you have any questions before the exam, please ask. If you have any questions during the exam, please ask the proctor. Open and start this exam when instructed. When finished, place your Scantron form in the appropriate stack and present your University ID Card to the proctor. You may keep the exam packet, so please show your work and mark the answers you selected on it. R = 0.0821 L•atm/mol•K 760 mm Hg = 760 torr = 1 atm m = mol/kg M = mol/L ΔTTf = imkf ΔTTb = imkb ΠV = nRTV = nRT kf (H 2 O) = 1.86 ºC/m kb(H 2 O) = 0.512 ºC/m kt A A o ln[ ]  RT Ea k Ae   Ka (CH 3 COOH) = 1.8 x 10- SC: 2r = s BCC: 4r = s√3 FCC: 4r = s√

Unit 1 Material (First assessed on Exam 1)

  1. There are ___ unpaired electrons in a ground-state oxide (O2-) ion. (A) 0 (B) 1 (C) 2 (D) 3 (E) 4
  2. The ground-state electron configuration of a magnesium ion (Mg2+) is: (A) 1s^2 2s^2 3s^2 3p^2 (B) 1s^2 2s^2 3s^1 (C) 1s^2 2s^2 2p^4 (D) 1s^2 2s^2 2p^6 3s^2 3p^2 (E) 1s^2 2s^2 2p^6
  3. Consider Mg2+, Mg, Cl-, and Cl. Which of the following statements is correct? (A) Cl-^ is smaller than Cl (B) Mg2+^ is smaller than Mg
  4. The Lewis Dot Structure of SiH 4 depicts: (A) There are no lone pairs of electrons (B) There is one lone pair of electrons (C) There are two lone pairs of electrons (D) There are four lone pairs of electrons (E) There are six lone pairs of electrons
  5. The carbon-oxygen bond order in the carbonate ion (CO 3 2-) is: (A) 1. (B) 1. (C) 1. (D) 1. (E) 2.
  1. The H-O-H bond angle in H 2 O is: (A) 90  (B) 120  (C) 109.5 (D) A little greater than 109.5 (E) A little less than 109.5
  2. The fluorine-sulfur-fluorine bond angle in SF 6 is: (A) 45  (B) 60  (C) 90  (D) 120  (E) 109.5
  3. A student ( ) proposes the Lewis Dot Structure below for the chlorate ion. Determine the formal charge on chlorine in this structure. (A) The chlorine has a formal charge of - (B) The chlorine has a formal charge of - (C) The chlorine has a formal charge of 0 (D) The chlorine has a formal charge of + (E) The chlorine has a formal charge of +
  1. Consider the molecule below and identify the correct statement. (A) There are 2 carbons that have sp^2 hybridization schemes (B) There are 3 carbons that have sp^2 hybridization schemes (C) There are 4 carbons that have sp^2 hybridization schemes (D) There are 5 carbons that have sp^2 hybridization schemes (E) There are 6 carbons that have sp^2 hybridization schemes Unit 2 Material (First assessed on Exam 2)
  2. The phase diagram below is for: (A) H 2 O (B) CO 2
  1. Sodium chloride melts at 804 ºC. Sodium iodide melts at 651 ºC. The difference in melting points can be attributed to: (A) Different intermolecular forces (dispersion, dipole-dipole, hydrogen bonding). (B) Different ionic charges (+ and -). (C) Different distances between nuclei (r). (D) Network covalent compounds.
  2. Consider H 2 O, NH 3 , CH 3 CH 2 CH 2 CH 2 OH, CH 3 CH 2 CH 2 OCH 3 , and HF. Which of these does not exhibit hydrogen bonding? (A) H 2 O (B) NH 3 (C) CH 3 CH 2 CH 2 CH 2 OH (D) CH 3 CH 2 CH 2 OCH 3 (E) HF
  3. Consider CH 3 CH 2 OH, CaO, CH 3 CH 3 , CaS, CH 3 OCH 3 , Ar. Arranged in increasing melting point, these are: Lowest melting point Highest melting point (A) CH 3 CH 2 OH < Ar < CH 3 CH 3 < CH 3 OCH 3 < CaO < CaS (B) Ar < CH 3 CH 3 < CH 3 OCH 3 < CH 3 CH 2 OH < CaS < CaO (C) Ar < CH 3 OCH 3 < CH 3 CH 3 < CH 3 CH 2 OH < CaO < CaS (D) Ar < CH 3 CH 3 < CH 3 OCH 3 < CH 3 CH 2 OH < CaO < CaS (E) Ar < CH 3 CH 3 < CH 3 CH 2 OH < CH 3 OCH 3 < CaO < CaS
  1. A student dissolves 12.000 g of an unknown polymer in 800 mL of water at 320 K. She measures the osmotic pressure to be 0.0677 mm Hg. What is the molar mass of the polymer? (A) 2.71 x 10^6 g/mol (B) 4.43 x 10^6 g/mol (C) 1.73 x 10^5 g/mol (D) 1.73 x 10^6 g/mol (E) 2.26 x 10^6 g/mol
  2. A student ( ) obtains a 120 gram sample of 198 Au (t1/2 = 2.70 days). How long will it take so that only 50.0 grams of 198 Au remain? (A) 3.60 days (B) 3.19 days (C) 6.48 days (D) 2.40 days (E) 3.41 days
  1. The following are initial rate data for: A + BC + D Experiment Initial [A] Initial [B] Initial Rate 1 0.10 0.10 0. 2 0.20 0.10 0. 3 0.10 0.20 0. (A) The rate law is Rate = k[A]^1 [B]^2 (B) The rate law is Rate = k[A]^2 [B]^1 (C) The rate law is Rate = k[A]^2 [B]^0 (D) The rate law is Rate = k[A]^0 [B]^1 (E) The rate law is Rate = k[A]^1 [B]^0 Unit 3 Material (Not previously assessed)
  2. As the reaction proceeds, the rate: (A) increases. (B) decreases. (C) remains constant.
  1. Consider the system 2 FeCl 3 (aq) + SnCl 2 (aq)  2 FeCl 2 (aq) + SnCl 4 (aq) Kc = 0. A student prepares the system and measures: [FeCl 3 ] = 0.120 M [SnCl 2 ] = 0.220 M [FeCl 2 ] = 0.166 M [SnCl 4 ] = 0.0923 M (A) The system is at equilibrium. (B) The system is not at equilibrium.
  2. The following reaction is at equilibrium: 2HBr (g)  H 2 (g) + Br 2 (g) ΔTHo^ = +72 kJ (endothermic) (A) The concentration of H 2 (g) increases when the system is heated. (B) The concentration of H 2 (g) decreases when the system is heated. (C) The concentration of H 2 (g) stays the same when the system is heated.
  3. The reaction below is at equilibrium. Which of the following statements is true? 2HBr (g)  H 2 (g) + Br 2 (g) ΔTHo^ = +72 kJ (endothermic) (A) The concentration of Br 2 (g) increases when H 2 (g) is added. (B) The concentration of Br 2 (g) decreases when H 2 (g) is added. (C) The concentration of Br 2 (g) stays the same when H 2 (g) is added.
  1. The pH of 0.0790 M HCl (aq) is: (A) 1. (B) 1. (C) 0. (D) 1. (E) -0.
  2. A student obtains 0.105 M CH 3 COOH (aq). The “ICE” table used to solve the equilibrium expression for this weak acid is: (A) CH 3 COOH (aq) + H 2 O (l) ^ CH 3 COO-^ (aq) + H 3 O+^ (aq) I 0 0.105 0. C +x +x +x E x 0.105+x 0.105+x (B) CH 3 COOH (aq) + H 2 O (l) ^ CH 3 COO-^ (aq) + H 3 O+^ (aq) I 0 0 0 C -x +x/2 +x/ E -x x x (C) CH 3 COOH (aq) + H 2 O (l) ^ CH 3 COO-^ (aq) + H 3 O+^ (aq) I 0.105 0 0 C -x +x/2 +x/ E 0.105-x x/2 x/ (D) CH 3 COOH (aq) + H 2 O (l) ^ CH 3 COO-^ (aq) + H 3 O+^ (aq) I 0.105 0.105 0. C -x +x +x E 0.105-x 0.105+x 0.105+x (E) CH 3 COOH (aq) + H 2 O (l) ^ CH 3 COO-^ (aq) + H 3 O+^ (aq) I 0.105 0 0 C -x +x +x E 0.105-x x x

grade computation details. Final exam keys, scores, and course grades will be posted on the CH 122 website as they become available.